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Titanium (III)reduction of dimethyl-glyoxime: Electrochemical and kinetic studies

Yashoda, M P and Padmalatha, * and Sherigara, B S and Nayak , P V (1999) Titanium (III)reduction of dimethyl-glyoxime: Electrochemical and kinetic studies. Indian Journal of Chemistry , 38A. pp. 176-179. ISSN 0975-0975

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Abstract

Titanium (III) mediated electroreduction of dimethyl glyoxime has been carried out in aqueous sulphuric acid medium and the reduction product has been isolated and characterized. The kinetic investigations have been carried out under stoichiometric and non-stoichiometric conditions at 306 K. It has been found that the reaction follows overall second order kinetics, first order each in [Ti(III)] and [DMG] and fractional order in sulphuric acid. The effect of varying concentrations of Ti(III), DMG, H2SO4, ionic strength and solvent composition has been studied. Effect of temperature has also been studied. Effect of temperature has also been studied and activation parameters have been computed from Arrhenius and Eyring plots.

Item Type: Article
Subjects: Engineering > MIT Manipal > Chemistry
Depositing User: MIT Library
Date Deposited: 21 Aug 2013 06:16
Last Modified: 05 Sep 2013 09:17
URI: http://eprints.manipal.edu/id/eprint/136840

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