Spectroscopic and structural study of the newly synthesized heteroligand complex of copper with creatinine and urea

Unnikrishnan, VK (2016) Spectroscopic and structural study of the newly synthesized heteroligand complex of copper with creatinine and urea. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 154. pp. 200-206. ISSN 1386-1425

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Abstract

Study of copper complex of creatinine and urea is very important in life science and medicine. In this paper, spectroscopic and structural study of a newly synthesized heteroligand complex of copper with creatinine and urea has been discussed. Structural studies have been carried out using DFT calculations and spectroscopic analyses were carried out by FT-IR, Raman, UV–vis absorption and fluorescence techniques. The copper complex of creatinine and the heteroligand complex were found to have much increased water solubility as compared to pure creatinine. The analysis of FT-IR and Raman spectra helps to understand the coordination properties of the two ligands and to determine the probable structure of the heteroligand complex. The LIBS spectra of the heteroligand complex reveal that the complex is free fromother metal impurities. UV–visible absorption spectra and the fluorescence emission spectra of the aqueous solution of Cu–Crn–urea heteroligand complex at different solute concentrations have been analyzed and the complex is found to be rigid and stable in its monomeric format very low concentrations.

Item Type: Article
Uncontrolled Keywords: Creatinine; urea; metal complexation; raman spectroscopy; UV–Vis spectroscopy; fluorescence spectroscopy.
Subjects: Departments at MU > Atomic Molecular Physics
Depositing User: KMC Library
Date Deposited: 21 Mar 2016 08:52
Last Modified: 21 Mar 2016 08:52
URI: http://eprints.manipal.edu/id/eprint/145595

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