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Electrosynthesis of aminotelechelic polyfacrylamide): Initiated by Ti(III)- NH20H redox system

Padmalatha, * and Sherigara, B S (1997) Electrosynthesis of aminotelechelic polyfacrylamide): Initiated by Ti(III)- NH20H redox system. Indian Journal of Chemistry, 36A. pp. 722-724. ISSN 0975-0975

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Abstract

Amino-terminated poly(acrylamide) of high molecular weight has been electrochemically synthesised, using titanium(III)-hydroxylamine redox system in aqueous sulphuric acid phase. Polymer is characterised by spectral analysis and molecular weight determination. Influence of various parameters like, concentration of titanium( lV) sulphate, hydroxylamine sulphate, sulphuric acid monomer, temperature and cathodic current on polymer yield has been studied. Suitable mechanism for Ti(Ill)-NH,OH initiated electro polymerisation of acrylamide is proposed

Item Type: Article
Subjects: Engineering > MIT Manipal > Chemistry
Depositing User: MIT Library
Date Deposited: 30 May 2016 10:13
Last Modified: 30 May 2016 10:13
URI: http://eprints.manipal.edu/id/eprint/146215

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