Synthesis, Characterization and Photophysical Studies of zinc(II) Complexes derived from a Hydralazine Hydrazone

Kulkarni, Suresh D (2018) Synthesis, Characterization and Photophysical Studies of zinc(II) Complexes derived from a Hydralazine Hydrazone. Journal of Photochemistry and Photobiology A:Chemistry, 351. pp. 225-230.

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Abstract

In the present study, we report two novel mononuclear zinc(II) complexes (1 and 2) obtained by reacting (E)-1-(phenyl(pyridin-2-yl) ethylene)- -(phthalazin-1-yl)hydrazine (L) with ZnCl2 and Zn(NO3)2�6H2O respectively. Photophysical properties of the compounds were studied in both solution and solid phase.The fluorescence absolute quantum yield of the complexes in solution varies in the order 1 (0.01) < 2 (0.030), on the other hand in the solid state it varies in the order 2(0.034) < 1(0.69). Quenching of fluorescence intensity of 2 in the solid-state has been attributed to intense and extensive non-covalent interactions present in the crystal structure. Theoretical calculations, density functional theory (DFT) and time- dependent density functional theory (TD-DFT) were also performed to support the experimental findings

Item Type: Article
Uncontrolled Keywords: Mononuclear zinc(II) complexes; Photophysical properties; Quenching; Non-covalent interactions; Computational studies
Subjects: Departments at MU > Atomic Molecular Physics
Depositing User: KMC Library
Date Deposited: 29 Jan 2018 09:08
Last Modified: 29 Jan 2018 09:08
URI: http://eprints.manipal.edu/id/eprint/150486

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