Conductivity/Electrochemical Study of Polyvinyl pyrrolidone-Poly(vinyl alcohol)/I3 Thin Film Electrolyte for Integrated Dye-Sensitized Solar Cells and Supercapacitors

Sangeetha, D N and Hegde, Nivedita and Poojari, Vidyashree G and Devadiga, Dheeraj and Sudhakar, Y N and Santhosh, M S and Selvakumar, M (2020) Conductivity/Electrochemical Study of Polyvinyl pyrrolidone-Poly(vinyl alcohol)/I3 Thin Film Electrolyte for Integrated Dye-Sensitized Solar Cells and Supercapacitors. Journal of Electronic Materials, 49 (11). pp. 6325-6335. ISSN 0361-5235

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Abstract

The current era focuses not only on producing solar energy but also preserving it for future use. Dye-sensitized solar cells (DSSC) and supercapacitors (SC) are such energy-based devices. DSSCs capture the solar energy and SCs store this captured energy. A natural anthocyanin dye extracted from Garcinia indica (kokum fruit) was used in the DSSCs. SnO2, one of the promising electrode materials for DSSC, was synthesized via a microwave technique. Blend polymer electrolytes (BPE) were prepared through a solution casting technique. A polyvinyl pyrrolidone (PVP) and polyvinyl alcohol (PVA) blend with varying concentrations of potassium iodide, along with iodine dopant, was prepared as a BPE electrolyte composition. The best of the PVA-PVP/KI composition was chosen using Nyquist plots of electrochemical impedance spectroscopy (EIS). Varying the temperature, the dielectric and conductivity study of the chosen composition was studied in detail. A fast/single-step synthesis technique, namely a laser-engraved approach, was used for few-layer graphene synthesis. This graphene serves as a common platform for the DSSC-SC integrated device: as a counter electrode in DSSC and graphenegraphene symmetric electrode in SC. A DSSC-SC integrated device was fabricated and characterized using various analytical and microscopy techniques. The integrated device showed a 0.42 fill factor and 0.56% efficiency. The discharge time for integrated DSSC-SC cells was found to be increased threefold

Item Type: Article
Uncontrolled Keywords: Dye-sensitizedsolarcell,supercapacitor, blend polymer electrolyte
Subjects: Engineering > MIT Manipal > Chemistry
Depositing User: MIT Library
Date Deposited: 01 Jan 2021 04:30
Last Modified: 01 Jan 2021 04:30
URI: http://eprints.manipal.edu/id/eprint/156171

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