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Methyl 2,6-bis[(5-bromo-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate

Fun, Hoong-Kun and Goh, Jia Hao and Rai, Sankappa and Isloor, Arun M and Shetty, Prakash (2010) Methyl 2,6-bis[(5-bromo-4,6-dimethoxypyrimidin-2-yl)oxy]benzoate. Acta Crystallographica Section E , 66 (7). p. 1871. ISSN 1600-5368

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Abstract

In the title compound, C20H18Br2N4O8, the interplanar angle of the pyrimidine rings is 75.1 (2)'. The central benzene ring is inclined at interplanar angles of 66.5 (2) and 71.9 (2)� with respect to the two pyrimidine rings. In the crystal structure, adjacent molecules are connected into two-molecule-hick arrays parallel to the bc plane via short Br...Br [3.5328 (12) A ° ] and Br...O [3.206 (3) and 3.301 (4) A ° ] interactions. A weak intermolecular aromatic stacking interaction [centroid–centroid distance = 3.526 (3) A ° ] is also observed.

Item Type: Article
Additional Information: © International Union of Crystallography
Uncontrolled Keywords: single-crystal X-ray study; T = 293 K; mean (C–C) = 0.007 A° ; R factor = 0.064; wR factor = 0.254; data-to-parameter ratio = 27.6.
Subjects: Engineering > MIT Manipal > Chemistry
Engineering > MIT Manipal > Printing and Media
Depositing User: MIT Library
Date Deposited: 10 Jan 2012 10:41
Last Modified: 10 Jan 2012 10:41
URI: http://eprints.manipal.edu/id/eprint/2064

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